PMID:17345747
| Citation |
'Kwong, HL, Yeung, HL, Lee, WS and Wong, WT (2006) Stereoselective formation of a single-stranded helicate: structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution. Chem. Commun. (Camb.) ':4841-3 |
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| Abstract |
Chiral C2-symmetric quaterpyridine L reacts with [Pd(eta3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium complex of formula [Pd2(eta3-C3H5)2(L)]2+; the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%. |
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